First if u want to send data over modbus then you need address, slave id and length..mean decide one address for sensor to read data and create slave id means sensor id and length means how many sensor data you want to send..like example:- like u said u have one voltage sensor to send data to modbus...let 1000 is the address of voltage sensor and 1 is salve id and 1 is length because u only have one sensor to send data... Just use write register to send data...check pymodbus client example to understand how it working.
And one more thing in modbus u have modbus master and modbus slave.
Read pymodbus documentation for more understanding. If still u have any query please feel free to ask.