Normally you can access contour data in the structure set with a call
like:
ss = dicom.read_file('rtss.dcm')
ss.ROIContours[0].Contours[0].ContourData
That should return a list of contour points [x0, y0, z0, x1, y1,
z1, ...]
You might try looking at the dicom file in dicompyler or using one of
the modules from the dicompyler code (that is built on top of
pydicom).
Much of the juiciest code is in dicomparser.py
http://code.google.com/p/dicompyler/source/browse/dicomparser.py
Roy