Hi Joao,
Only the DAC 1 and DAC 2 BNC connectors can be used for analog output. To use them as analog outputs you need to instantiate a pyb.DAC object.
DAC1 = pyb.DAC(1) # Instantiate DAC object.
DAC1.write(0) # set the voltate to 0.
DAC.write(255) # Set the voltate to its maximum value (by default DAC is 8 bit but can be specified to be 12 bit, see docs linked above).
Did you do this before doing the voltage measurements?
All the BNC connectors on the breakout board connect directly to pins on the pyboard microcontroller, so it is in principle possible to damage them by applying too much voltage. I don’t think the voltage measurement you did so far are definative though as unless you have specified them as an output and set the voltage they will be floating. I suggest testing them using the standard pyControl digital input/ouput classes to see if they are OK. If they have got damaged you can replace the pyboard, as it is connected to the breakout board using connectors rather than being soldered on.
best,
Thomas