Hi Mark,
I do not think there is a connection between the two parameters in the way you suggest. Both parameters feed into the empirical expressions for F1 and F2 so there is no real requirement for any logical consistency: the most important thing is to use the same as was used when the coefficients for those expressions were determined. Incidentally this also means using the same air mass model that was used originally (see perez_driesse() helper function _calc_delta() ).
Note that altitude has a strong effect on (absolute) air mass, but only a secondary effect on (apparent) zenith angle because it only affects refraction.
Does that help?
Anton
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