For the benefit of anyone else experiencing this issue:
To resolve it, I went to:
https://www.sdrplay.com/downloads/
and selected RSPduo (this was just at random, I don’t know if it makes a difference) and Windows 10, and then selected to download ‘SDRuno’. I installed it, accepting all the defaults. After that, Pothos didn’t generate an error, and I was able to successfully use the SDR Sink.
I’m still learning how to configure that, but for now what worked was:
(a) set Device Args drop-down to “LimeSDR-USB”
(b) set the Sample Rate to 5e6
(c) in the Channels tab, set Frequency to the desired transmit frequency, e.g. 100e6 (obviously terminate the SDR into a load or elsewhere, rather than transmit to the air).
The above steps generate the transmission on both outputs of the LimeSDR. I don’t know what value to type where, to select a particular channel currently.