Casey,
The boot files for the PiDP-8/I are in the RasPi OS directory:
/opt/pidp8i/share/boot
The files are named 0.script, 1.script, 2.script, ... where the digit in the file name corresponds to the IF switch configuration when you trigger the boot into that particular configuration. I will assume for now that you are booting into normal OS/8 where the IF switch configuration is octal 0 (binary 000). The corresponding file would be /opt/pidp8i/share/boot/0.script. You can open that file using the RaspPi OS text editor (which is very straightforward) and just add that command.
If, as an example, you want to boot into a configuration using IF switches set to 6 octal (binary 110) then the proper boot file would be /opt/pidp8i/share/boot/6.script.
You also have the option of first experimenting without editing the boot script file. Simply boot into the unmodified configuration you want to experiment with. While that configuration is running, type Control/E on the console terminal. This will drop you into SIMH. Just directly type that "set console ..." command to the simh prompt. Then type "g" or "go" to the next simh prompt to restart the simulator. If there is some problem, you can Control/E back into simh and try a different command. Once you're sure you have the command you want, then you can edit that command into the appropriate /opt/pidp8i/share/boot/*.script file. From then on, that command will be executed every time you boot into that configuration.
Cheers,
-- steve