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Dear Naseer
I agree with raghavan. If you want to calculate crystallite size (not particle size) and FWHM, you have to do XRD.
Thanks,
With Regards,
Prashant
Gujarat
Uv data peak represents distribution of silver nano particles
If peak is wide agglomeration or poly distribution of particles
Peak is narrow crystalline structure
Particle size can be find from scanning electron microscope is better