The CMOS and NMOS version of the 6532 are identical (minus a one count difference in the timer according the datasheets).
PAL-1s and KIM-1s all use the NMOS variant, the CMOS variant is very rare.
To use IRQ on the KIM-1 /PAL-1/2 is up to the user. The line is there on the expansion connector, the ICs IRQ lines are connected. Nothing in the KIM-1 monitor uses interrupts.
Connecting PB7 to IRQ is possible. But beware, other IRQ sources will fight with PB7 as output as PB7 not an open collector line. Limit to PB7 only or insert an open collector port in between.