Hi, we haven't yet set rate limits, though likely Wii next year. Over time the best strategy for matching ORCID iDs to people is to have the person provide an authenticated ORCID iD. You would add a button on your site, usually tied to the person's account, and the button would initiate ORCID providing your system an iD. More details at http://members.orcid.org/api/tutorial-retrieve-orcid-id-curl-v12-and-earlier
If you are looking for general info I just got some benchmarking, we just released the public data file for 2015. You can find it at http://dx.doi.org/10.6084/m9.figshare.1582705.
Best, L
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