If you're asking whether there is anything you can say about how close the best solution found by the time limit is to the optimal solution (as a ratio), the answer is no.
To put it another way, the LP algorithm starts at an initial solution, x_init, and ends at the optimal solution, x_opt, but it can take an arbitrarily long time to get there. Whatever time limit L you set, there is an LP problem for which the progress of the algorithm by time L can look like this (assuming it's a maximization problem):
x_init x_best_sol_by_L x_opt
Specifically, the ratio of the distances (x_best_sol_by_L - x_init) / (x_opt - x_init) can be arbitrarily close to 0.