Hi Christian,
Be aware that just executing G0 A90
will not give you a reliable indication, because the rotation then
depends on where the A axis was before that commend (unless you
are in relative mode, which is usually not the case, and would be
problematic in itself).
Instead execute:
G0 A0
to reset A to zero degrees.
Then execute
G0 A360and look at some set screw or similar to see whether the axis
does exactly one turn.
If not, you need to adjust the steps per mm (or per degree). But
those are not in the machine.xml,
this is a matter of the controller configuration i.e. in
Marlin (I believe in a header file, to be compiled).
Note, you can enter the Steps per Unit in OpenPnP, but only as a means to let OpenPnP passively know the resolution of the axis, this will not configure Marlin for you 😁:

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> Where is the steps per unit used inside of OpenPnP?
It is used here:

_Mark