OLA is software and 0-10V is not.
You need to develop some hardware to generate the signals that you want.
Once you have an idea for such hardware you can think about how it
would interface with the rest of the world.
OLA could be a nice part of that, an embedded Linux system could also
be a nice part of that. But the only reason to choose an rpi would be
that you want to avoid learning how to build an embedded Linux
yourself, and even then there are better choices. The rpi is not
particularly nice hardware.
//Peter