The SystemControlHighlightListAccent
MediumBrush is not used at all in the actual files list - it was used before and was left there in settings and I forgot that there is a layer underneath the file that doesn't show in settings. I'll update that soon
That is tricky because the default brushes have opacity and/or color with alpha, so you'd have to adjust opacities manually until they match
You can try something like this
<SolidColorBrush x:Key="SystemControlHighlightListLowBrush" Color="#5E81AC" />
<SolidColorBrush x:Key="SystemControlHighlightListAccentLowBrush" Color="#5E81AC" />
I might need to update the theming system at some point as I am not fan of how Microsoft themes are mixing alpha and opacity in the same brush, probably hurting rendering performance at the same time. But that probably won't happen anytime soon.
By the way, make sure you are working on a copy of the theme folder so the update doesn't overwrite your changes. If you have two xaml files, it will load both, and whatever loads last will overwrite previous keys... plus it takes longer to load or reload the theme