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Paul (et al):
I was a tech service rep for an international ink and coatings manufacturer for a number of years. UV cure coatings were our bread and butter. I was in the printing industry for over 40 years.
Simply put , this product “comes off in a shell” for you because it did not crosslink completely. This is a common technical issue.
UV cure product are considered 100% solids. They are made up of pigments, monomers, oligomers and photo-initiators which when exposed to the correct range and intensity of light crosslink or polymerize. It is very easy to undercure UV coatings and even if the coating appears to have hardened it still may not adhere to the guitar.
For the purpose of this discussion we need to understand that even with clear products application film thickness is critical, as is the proper wavelength and intensity of light. Both factors effect our ability to cure the coating. Again think of the light as the catalyst, too little or too much and you have an incomplete chemical reaction and a possible failure.
As a UV cure product begins to harden/crosslink with exposure to light, it also begins to become more opaque to that light energy. So, it is critical that the intensity of the light (in the proper wavelength range) is enough to penetrate the coating, bounce off the surface of the substrate (in this a case a porous wood) and exit the coating before the coating becomes opaque to the UV.
If the UV light energy is not intense enough to penetrate the full coating thickness and return, then a top cure condition can be created. This condition means that you have a hard layer of finish floating on top of a thin film of uncured material that may never finish crosslinking.
The problem of light intensity becomes more critical when pigments are added (think pore fillers , or solid colors). UV Cure products that contain black , white, yellow, blue or green pigments can add significant exposure time / intensity requirements to the cure as these pigments absorb UV energy. Remember the light must penetrate to the surface of the deepest pore in the wood and bounce back through the coating film in order to properly crosslink the coating/filler.
In the printing industries for example, UV coating thicknesses are controlled to ensure proper cure and are ideally in the 8-15 micron range on flat, relatively clean, non oily, non porous surfaces; products that are nothing like the woods used in lutherie. for comparison purposes spray on UV cure finishes suggest that they can be applied up to 3 mil thick, but must be cured with light in the 365nm range @ 1W/cm2 intensity. In production environments light energy needs to be focused, controllable and monitored because the coating or film must be exposed to a certain range of energy for a certain duration to ensure a complete cure.
So far we have been discussing coatings on a “flat” surface where the distance from the light source can be controlled , the light can be focused with reflectors to maximize its effect at a specific height from the coated surface and the energy being applied can be monitored by a radiometer that is measuring light at the specific distance from the lamp. Another reason for monitoring output is that UV lamps degrade over time, with some types losing 40-60% of their output after less than 500 hours. So printers and most other industrial users of UV cure products employ a device called a radiometer to monitor the output of their light sources. Modern LED lamps do not degrade as quickly as traditional mercury lamps but the coatings selected must be compatible with the output characteristics of the lamp(s).
Now imagine the chaos created by a three dimensional object with a porous surface , which limits your ability to control the coating thickness, the actual time, and energy application to all surfaces equally during the process. As you can see, the issues that effect proper UV curing on a guitar are compounded by its shape and the materials from which it is made.
The irregular shape of a guitar, makes focusing light energy more difficult, the natural oiliness of some woods can act as a surface contaminant / barrier preventing adhesion, the pores make the surface irregular leading to potentially uncured material being trapped under the surface and reducing adhesion. So surface prep becomes another critical factor, some very oily woods and may in fact require another product that acts as a barrier / bonding layer to allow the finish clear to adhere properly.
Adhesion testing on samples is fairly simple procedure called a “cross hatch tape test”. There are many videos on this procedure available online.
All this is why products that advertise/ highlight the feature that they can be cured in the sun present severe credibility issues for me; and in truth, I tend to view these claims as hyperbolic at best, and flat out deception at worst.
Yes, UV cure coatings will "harden" in the sun.
Unfortunantly none of us can control the amount of uv exposure, and effect a consistent cure, and subsequently good adhesion, by using the sun as a light source. It is at best an unreliable curing method, at worst it is a recipe for expensive failures.
Time of day, latitude, season, cloud cover, altitude, air quality (ozone), and solar activity all effect the amount of UV available. Something that “worked” fine today may not tomorrow, or next month. I put worked in quotes because my definition of “worked” includes not being subject to catastrophic failure or delamination in the foreseeable future. As a small builder/hobbyist I don't want to spend my limited time and resources dealing with finish failures.
Caveat Emptor. Get the technical data sheets for any UV cure product you are considering, compare the wave langths (Nanometers) and power requirements (Millijoules of energy) match it with an appropriate light source and follow the instructions from both manufacturers rigourously, control the film thickness and you have a fighting chance of success.
Finally, adopting UV cure coatings is a decision usually driven by the need for high production speeds, and waste stream reduction. There are viable UV cure systems for guitar makers but the ROI doesn’t work for me given the small number of instruments that I build annually. Hope this helps.
I apologize if this is overlong - editing is not my strong suit, "tech dump" is my default setting.
Best
Fred
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