Hi Anita,
your data is a compressed adjacency list format that nwimport does not natively understand. It wants one edge/arc per line.
But there is a simply way to load your data with nwfromedge. First, save your .xlsx file as .csv file in Excel. The code below imports the data as csv (you need to change your file destination), reshapes it and runs nwfromedge.
Have fun!
Thomas
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// loads data as .csv => adjust your path
import delimited "/Users/thogr49/Documents/USStateAdjMat.csv", delimiter(comma) clear
// reshapes the data
rename v1 ego
reshape long v, i(ego) j(j)
rename v alter
// needed to deal with isolates
replace alter = ego if alter == ""
nwfromedge ego alter
nwplot network, lab