Hi,
answer to Q1 is: when you create the wifi NetDevice you have to set the channel. if you use different channels, they'll be orthogonal (no interference). As a consequence, the answer is simply: use two different Wi-Fi NetDevices.
Answer to Q2 is far more complex, and it can be summarized as: "you are not prepared". Literally.
In order to do what you're thinking you'll probably need a (multihop) routing algorithm, an addressing scheme, etc. First you must design your system (in a way that is reasonably right), then you'll have to implement it. No "snippets" can help you in this.
there could be an easy way to do this, but I'm not going to explain it (sorry) as it would be MY way, and not your. it's not a matter of coding, it's research.
I mean, one thing is to ask how to setup OLRS to use different interfaces, another thing is to build a whole system. isn't it ?
Summarizing: design first, then you'll find a way.
T.