I had quick look, there doesn't seem much to program and your thermostat is responding to HTTP requests so NR seems like a good way to control it.
1) test the GET commands in your browser
2) the basic flow you need in NR would be "Inject" + "HTTP request" ... begin by using the same parameters as in step 1 (same URL etc)
3) try one POST command with visible feedback on your thermostat (I don't know, setpoint change, mode change, whatever) and try to POST that command using NR