> When I want to assign the second device to the rear, the position is grayed out / not selectable.
Which exact screen are you looking at? Can you show the URL from the browser URL bar, and a screenshot? By "greyed out", you don't mean pink stripes do you?
You've already said that you can create a device by clicking on the rear elevation, and obviously if you click on the front elevation it will be occupied.
I am wondering: did you do Device > Add (taking you to /dcim/devices/add/), select Rack Face: Rear, and then try to select the U-position from the drop-down? Testing this, it looks like the Rack Position drop-down *doesn't* update when you do this, and it should. If that's what you're describing, then I suggest you raise a bug report: give the step-by-step instructions to reproduce.
[or else: the drop-down should show all U positions where either the front *or* rear faces are unoccupied]