Many of your tubes probably should be in your semiconductor collection.
And, if semiconductor is a dirty word, then in the bin !
Reference:- Kohl, Materials and Techniques for Electron Tubes A completely revised edition of Materials Technology for Electron Tubes., 1960, Reinhold.
Page 551 describes Barium-Strontium-Calcium Oxide Cathodes, as "most widely used at the present time in receiving tubes, cathode ray tubes, picture tubes, and similar devices".
Wait for it.... "Oxide cathodes are n-type semiconductors....".
sorry guys, I hope there aren't too many tears out there,
John K
Australia.