i test the same main with out nacl,it is work fine.
F:\work\naclsdk_win\pepper_46\examples\tutorial\using_ppapi_simple>make
F:/work/naclsdk_win/pepper_46/tools/make -C F:\work\naclsdk_win\pepper_46/src/ppapi_simple STAMPDIR=F:/work/naclsdk_win/pepper_46/examples/tutorial/using_ppapi_simple/glibc/Release
F:/work/naclsdk_win/pepper_46/examples/tutorial/using_ppapi_simple/glibc/Release/ppapi_simple.stamp
make[1]: Entering directory 'F:/work/naclsdk_win/pepper_46/src/ppapi_simple'
make[1]: Leaving directory 'F:/work/naclsdk_win/pepper_46/src/ppapi_simple'
F:/work/naclsdk_win/pepper_46/tools/make -C F:\work\naclsdk_win\pepper_46/src/nacl_io STAMPDIR=F:/work/naclsdk_win/pepper_46/examples/tutorial/using_ppapi_simple/glibc/Release
F:/work/naclsdk_win/pepper_46/examples/tutorial/using_ppapi_simple/glibc/Release/nacl_io.stamp
make[1]: Entering directory 'F:/work/naclsdk_win/pepper_46/src/nacl_io'
make[1]: Leaving directory 'F:/work/naclsdk_win/pepper_46/src/nacl_io'
CC glibc/Release/hello_world_x86_64.o
LINK glibc/Release/using_ppapi_simple_unstripped_x86_64.nexe
libavformat.a(udp.o): In function `udp_close':
/home/baisy/pepper/naclports/out/build/ffmpeg/ffmpeg-2.6.1/libavformat/udp.c:934: warning: warning: pthread_cancel is not implemented and will always fail
libavformat.a(rtpdec.o): In function `ff_rtp_parse_open':
/home/baisy/pepper/naclports/out/build/ffmpeg/ffmpeg-2.6.1/libavformat/rtpdec.c:537: warning: warning: gethostname is not implemented and will always fail
VALIDATE glibc/Release/using_ppapi_simple_unstripped_x86_64.nexe
STRIP glibc/Release/using_ppapi_simple_x86_64.nexe
CREATE_NMF glibc/Release/using_ppapi_simple.nmf
thanks!