I, too, am interested in clarifying this point (apologies if it's been answered elsewhere, and bear with me as I reason this out to myself..)
Orthotropic means the properties of a material vary in 3 orthogonal directions. Wood is an orthotropic material because the properties vary. A rolled plate is also described as orthotropic (but not because the sample itself is typically rectangular. Instead, it is because the properties are different in the longitudinal, transverse, and normal directions.)
Orthorhombic is traditionally used to describe crystal structures only. The definition is "of, relating to, or constituting a system of crystallization characterized by three unequal axes at right angles to each other." So the key here is that the lengths vary in three directions.
So, wood is an orthotropic material. However, unless i cut it into a rectangular block it would have no characteristics being described as orthorhombic.
Similarly, if I cut my rolled plate into a cube specimen I am left with an orthotropic material without orthorhombic symmetry.
It's a very slight difference, and I'd be happy if someone can correct me! But I believe a rolled plate should have a specimen symmetry described as "orthotropic" and not orthorhombic.
That's all just semantics, though, if the code is accounting for the variation in material properties in 3 directions by inputting SS=orthorhombic