Vat Blue 20
Ceola Roefaro
Blue has been an important colour in art and decoration since ancient times. The semi-precious stone lapis lazuli was used in ancient Egypt for jewellery and ornament and later, in the Renaissance, to make the pigment ultramarine, the most expensive of all pigments.[3] In the eighth century Chinese artists used cobalt blue to colour fine blue and white porcelain. In the Middle Ages, European artists used it in the windows of cathedrals. Europeans wore clothing coloured with the vegetable dye woad until it was replaced by the finer indigo from America. In the 19th century, synthetic blue dyes and pigments gradually replaced organic dyes and mineral pigments. Dark blue became a common colour for military uniforms and later, in the late 20th century, for business suits. Because blue has commonly been associated with harmony, it was chosen as the colour of the flags of the United Nations and the European Union.[4]
In the United States and Europe, blue is the colour that both men and women are most likely to choose as their favourite, with at least one recent survey showing the same across several other countries, including China, Malaysia, and Indonesia.[5][6] Past surveys in the US and Europe have found that blue is the colour most commonly associated with harmony, confidence, masculinity, knowledge, intelligence, calmness, distance, infinity, the imagination, cold, and sadness.[7]
The term blue generally describes colours perceived by humans observing light with a dominant wavelength between approximately 450 and 495 nanometres.[12] Blues with a higher frequency and thus a shorter wavelength gradually look more violet, while those with a lower frequency and a longer wavelength gradually appear more green. Purer blues are in the middle of this range, e.g., around 470 nanometres.
Isaac Newton included blue as one of the seven colours in his first description of the visible spectrum.[13] He chose seven colours because that was the number of notes in the musical scale, which he believed was related to the optical spectrum. He included indigo, the hue between blue and violet, as one of the separate colours, though today it is usually considered a hue of blue.[14]
In painting and traditional colour theory, blue is one of the three primary colours of pigments (red, yellow, blue), which can be mixed to form a wide gamut of colours. Red and blue mixed together form violet, blue and yellow together form green. Mixing all three primary colours together produces a dark brown. From the Renaissance onward, painters used this system to create their colours (see RYB colour model).
The RYB model was used for colour printing by Jacob Christoph Le Blon as early as 1725. Later, printers discovered that more accurate colours could be created by using combinations of cyan, magenta, yellow, and black ink, put onto separate inked plates and then overlaid one at a time onto paper. This method could produce almost all the colours in the spectrum with reasonable accuracy.
On the HSV colour wheel, the complement of blue is yellow; that is, a colour corresponding to an equal mixture of red and green light. On a colour wheel based on traditional colour theory (RYB) where blue was considered a primary colour, its complementary colour is considered to be orange (based on the Munsell colour wheel).[15]
In 1993, high-brightness blue LEDs were demonstrated by Shuji Nakamura of Nichia Corporation.[16][17][18] In parallel, Isamu Akasaki and Hiroshi Amano of Nagoya University were working on a new development which revolutionized LED lighting.[19][20]
Nakamura was awarded the 2006 Millennium Technology Prize for his invention.[21]Nakamura, Hiroshi Amano and Isamu Akasaki were awarded the Nobel Prize in Physics in 2014 for the invention of an efficient blue LED.[22]
Blue is the colour of light between violet and cyan on the visible spectrum. Hues of blue include indigo and ultramarine, closer to violet; pure blue, without any mixture of other colours; Azure, which is a lighter shade of blue, similar to the colour of the sky; Cyan, which is midway in the spectrum between blue and green, and the other blue-greens such as turquoise, teal, and aquamarine.
Blue also varies in shade or tint; darker shades of blue contain black or grey, while lighter tints contain white. Darker shades of blue include ultramarine, cobalt blue, navy blue, and Prussian blue; while lighter tints include sky blue, azure, and Egyptian blue (for a more complete list see the List of colours).
In nature, many blue phenomena arise from structural colouration, the result of interference between reflections from two or more surfaces of thin films, combined with refraction as light enters and exits such films. The geometry then determines that at certain angles, the light reflected from both surfaces interferes constructively, while at other angles, the light interferes destructively. Diverse colours therefore appear despite the absence of colourants.[25]
Egyptian blue, the first artificial pigment, was produced in the third millennium BC in Ancient Egypt. It is produced by heating pulverized sand, copper, and natron. It was used in tomb paintings and funereal objects to protect the dead in their afterlife. Prior to the 1700s, blue colourants for artwork were mainly based on lapis lazuli and the related mineral ultramarine. A breakthrough occurred in 1709 when German druggist and pigment maker Johann Jacob Diesbach discovered Prussian blue. The new blue arose from experiments involving heating dried blood with iron sulphides and was initially called Berliner Blau. By 1710 it was being used by the French painter Antoine Watteau, and later his successor Nicolas Lancret. It became immensely popular for the manufacture of wallpaper, and in the 19th century was widely used by French impressionist painters.[26] Beginning in the 1820s, Prussian blue was imported into Japan through the port of Nagasaki. It was called bero-ai, or Berlin blue, and it became popular because it did not fade like traditional Japanese blue pigment, ai-gami, made from the dayflower. Prussian blue was used by both Hokusai, in his wave paintings, and Hiroshige.[27]
In 1824 the Societ pour l'Encouragement d'Industrie in France offered a prize for the invention of an artificial ultramarine which could rival the natural colour made from lapis lazuli. The prize was won in 1826 by a chemist named Jean Baptiste Guimet, but he refused to reveal the formula of his colour. In 1828, another scientist, Christian Gmelin then a professor of chemistry in Tbingen, found the process and published his formula. This was the beginning of new industry to manufacture artificial ultramarine, which eventually almost completely replaced the natural product.[28]
In 1878 German chemists synthesized indigo. This product rapidly replaced natural indigo, wiping out vast farms growing indigo. It is now the blue of blue jeans. As the pace of organic chemistry accelerated, a succession of synthetic blue dyes were discovered including Indanthrone blue, which had even greater resistance to fading during washing or in the sun, and copper phthalocyanine.
Blue dyes are organic compounds, both synthetic and natural.[30] Woad and true indigo were once used but since the early 1900s, all indigo is synthetic. Produced on an industrial scale, indigo is the blue of blue jeans.
Certain metal ions characteristically form blue solutions or blue salts. Of some practical importance, cobalt is used to make the deep blue glazes and glasses. It substitutes for silicon or aluminum ions in these materials. Cobalt is the blue chromophore in stained glass windows, such as those in Gothic cathedrals and in Chinese porcelain beginning in the Tang dynasty. Copper(II) (Cu2+) also produces many blue compounds, including the commercial algicide copper(II) sulfate (CuSO4.5H2O). Similarly, vanadyl salts and solutions are often blue, e.g. vanadyl sulfate.
When sunlight passes through the atmosphere, the blue wavelengths are scattered more widely by the oxygen and nitrogen molecules, and more blue comes to our eyes. This effect is called Rayleigh scattering, after Lord Rayleigh and confirmed by Albert Einstein in 1911.[32][33]
The sea is seen as blue for largely the same reason: the water absorbs the longer wavelengths of red and reflects and scatters the blue, which comes to the eye of the viewer. The deeper the observer goes, the darker the blue becomes. In the open sea, only about 1% of light penetrates to a depth of 200 metres (see underwater and euphotic depth).
The colour of the sea is also affected by the colour of the sky, reflected by particles in the water; and by algae and plant life in the water, which can make it look green; or by sediment, which can make it look brown.[34]
The farther away an object is, the more blue it often appears to the eye. For example, mountains in the distance often appear blue. This is the effect of atmospheric perspective; the farther an object is away from the viewer, the less contrast there is between the object and its background colour, which is usually blue. In a painting where different parts of the composition are blue, green and red, the blue will appear to be more distant, and the red closer to the viewer. The cooler a colour is, the more distant it seems.[35] Blue light is scattered more than other wavelengths by the gases in the atmosphere, hence our "blue planet".
Some of the most desirable gems are blue, including sapphire and tanzanite. Compounds of copper(II) are characteristically blue and so are many copper-containing minerals.Azurite (Cu3(CO3)2(OH)2), with a deep blue colour, was once employed in medieval years, but it is unstable pigment, losing its colour especially under dry conditions. Lapis lazuli, mined in Afghanistan for more than three thousand years, was used for jewelry and ornaments, and later was crushed and powdered and used as a pigment. The more it was ground, the lighter the blue colour became. Natural ultramarine, made by grinding lapis lazuli into a fine powder, was the finest available blue pigment in the Middle Ages and the Renaissance. It was extremely expensive, and in Italian Renaissance art, it was often reserved for the robes of the Virgin Mary.