Is there a specific problem you are trying to solve by wanting to override how it works?
There is no scheduler to speak of that you can override.
What happens is that each of the daemon process when using daemon mode uses a cross process mutex lock on being able to accept the next connection. A process will only attempt to acquire the cross process mutex lock if they have a spare thread available ready to handle a request.
This mechanism ensures you don't end up with the greedy acceptor problem where a process accepts connections it isn't in a position to handle immediately, but also avoids the thundering heard problem.
Since the cross process mutex lock only comes into play for the accept phase of a handling the connection and is then released, even though that same process may still have idle threads in its thread pool, it is more likely that a different process which is more ready gets the lock the next time. The result of this is that acceptance of requests should be relatively balanced across the processes.
That you are even asking suggests you think you have a problem where you need more control. If your overall application handles various workloads (via request handlers), there are perhaps better ways of dealing with it by partitioning the URL namespace and directing requests to different daemon process groups, each configured differently for that subset of requests directed to it.
So as already asked, if you can explain what the problem is that you think you have, I can perhaps suggest more appropriate ways of dealing with it.
Graham