I looked at your site by copying the home page and running mod_pagespeed over it.
Regarding combine_css, I looked at recipe.css and welcome.css and they both reported that they could not be combined because of parse errors. This was reported in Apache's error log (I have debug log level turned on).
Our CSS parser handles much of CSS2.1 and only a little of CSS3, and apparently it can't handle yours.
I suspect you're using CSS3 constructs but you could check by running the files through an online CSS validator.
Regards, m.