You want to do convert the ascii character represented as Dec.
App Inventor does not have a function to do that. A simple way to convert would be to use two Lists as a conversion lookup table and then use the pairs
block.to convert each character to dec.
char Dec
LIst1 List2
A 65
B 66
C 67
D 68
..
Z 90
0 48
1 49
2 50
..
9 57
Another way would be to use a Procedure like this perhaps

where the join blocks look like this
0,1,2,3,4,5,6,7,8,9,
:,;,<,=,>,?,@,
A,B,C,D,E,F,G,H,I,J,K,L,M,N,O,P,Q,R,S,T,U,V,W,X,Y,Z The characterList is a List created from a simple csv text file (this is the join block)
You can convert the other way if you make the companion Procedure DecToChar .
I am not sure where you go from here; Is TAG1 supposed to be 8465711 ? If so more work will be required to get this in the form you require. You would probably 'read' each character separately using the red Text blocks, convert the character to a Dec value and save it to a checksum string ( the numerical string 8465711) and add that to a list of check sums that you want to save and perhaps print? Or something else. ?
Regards,
Steve