I believe in fact it is a bug of App Inventor, since you can save a picture in the canvas, in FIXED mode and the picture doesn't degrade too much.
The bigger degradation (I think due to a high compression value) only happens when the screen is set to RESPONSIVE.
Outside App Inventor, that kind of blurring usually happens when saving a JPG with a compression of 85% or more, but in App Inventor, it happens even when saving in PNG format.