Done is done .. there is no event handler to do what you hope to do.
Text boxes are usually used with the Button component, with the user clicking on the button when text entry is complete. http://ai2.appinventor.mit.edu/reference/components/userinterface.html#TextBox
Users have used various gimmicks to avoid this issue and avoid Done: Using a Clock object they count the length of the Text box and if 1 digit do... or 2 digits do ... or 3 so the clock is continually checking the length of the textbox..when the checking finds the expected number of digits, the event handler in the Clock automatically 'submits'... It woud require the user to enter 001 or 021 or 100 for 1 or 21 or 100. It would work...
I am not sure you understood what I said... the user does NOT have to use the Done button; she/he can go directly to your Submit button and the Submit will use whatever values were input on the keyboard.
That will give a single button submittal, however there is no way to re-purpose Done.