App Inventor does not have a control that lists the files in a folder and that would let you select a mp3 file.
To select a music file without that control, you could make a list of all the files you want to have in your app that are in your music folder. Put the names of those music file in a List. Also note the Path to the music folder. Use a ListPicker control to select the music you want . Use code something like Path + musicfile.mp3 to start a particular music file.
An alternative way is to use the ActivityStarter to turn on the File Manager app that is probably already on your app and use that to select files (a bit awkward, but the technique works)..
You are going to have to experiment Billy. Do you know how to use Lists and a ListPicker?
Regards,