I think the issue here is that in your Arduino sketch you are calling Serial.read() and passing the value to the Bluetooth serial port.
Serial.read() only returns a single byte, which will then be sent to App Inventor.
When you attempt to split on ',', this will result in a list of length 1 with the single byte included. Your blocks code attempts to extract 3 elements when only one exists, hence the error.
Assuming that you are writing to Serial for debugging purposes, you may want to consider constructing a
String by concatenating the values and then write the String both to Serial and Bluetooth.
Regards,
Evan