Buttons and the Canvas do not have any property that allows a shadow with App Inventor.
You can simulate this effect by creating your own button image...a png image perhaps that has a 'shadow' created using an image manipulation program like GIMP 2.
aspect ratio as your button. Place the image in Button.Image
Try it and let us know how it works for you.
Similarly, you could use an image for the Canvas background perhaps. Use Canvas.BackgroundImage.
Regards,
Steve