I dont believe so, a lot of the WE commands rely on the player location to execute. In 1.7.10 there was no way to do this, and I would hazard that even if you tried it in 1.8.9 using the ~ ~ ~ notation within Minecraft, that WE would still not allow this to happen. I also, depending on what you are planning and your version, believe that in 1.8.9 there is the /clone command that might allow you to 'replace' an area in WE like fashion.
My understanding is that you can have the structure within your world, and then when you run the /clone command you tell it what to clone, and where to place it. But again, going to require you to have 1.8.9 to do so. All of the above is assuming you are using the old MinecraftEdu java version, not the current Minecraft: Education Edition.
Elfie.