I understand you problem, you are not alone as I have also problems with this particular feature.
Theoretically there are a few "corrections" that may help but when you start digging it becomes obvious that there is only one solution.
Let's assume that the midi controller can be convinced to reverse the encoder scale, meaning left is 127 and right is 0, then turning
the encoder will be opposite to the movement of the slider, turn the knob left and the slider will go to the right because for the slider
the minimum is left and maximum is right. The other thought to use negative values you cannot be done because MIDI does not support this.
The "simplest" workaround could be to make a change in the module to invert the value of "Post-Crop Vignetting Amount", this could be applied
to the MIDI value (0..127) or to the internal representation (0.0..1.0), that would cause the slider to go right when you turn left, that is after some
more changes have been made in the MIDI output path. Now it becomes difficult because changing the "Post-Crop Vignetting Amount" is not just MIDI to LR,
it also involves LR to MIDI (encoder) and LR to MIDI (led) and MIDI to MIDI (internal). When you use the mouse to move the slider the new value is used to update the MIDI controller, which means that the internal LR value is translated to an inverted MIDI value which is send to the controller, this value is used to update the internal encoder value and the LED display. At this point another difficulty surfaces, the LED moves from left to right but inverted it has to move from right to left meaning from 127 to 0, which is something the MIDI controller does not support. At this moment in time I give up because this "issue" can not be solved in MIDI2LR, the only place would be to change the working of the slider in LR. But you will never be able to convince Adobe because there you will receive the same explanation as already provided: you vary the amount (intensity) from 0 (left) to 100(right) (which is the same logic as exposure).
You are right, somehow the "Post-Crop Vignetting Amount" works "differently" but when you look at the way LR works it makes sense because the vignette is a (filter) mask and you vary the amount of effect within this mask which is very different from varying the projection of an (vignette) overlay onto the photo. The same logic applies to every filter (Gradient, Radial, Adjustment Brush): to darken/reduce you move the slider/knob to the left.