Micro: Needle Like structure
Hardness: 300 to 350 VHN
Regards,

Untempered martensite harness is approximately 60 – 65 HRc and not as soft as 300 to 350 Vickers as has been suggested
John du Plessis
Technology Manager
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Dear Babu,
Untempered Martensite is brittle in nature, which will have high hardness level. Martensite will be formed in carbon and low alloy steel, when the cooling rate is higher than the critical cooling rate. For example, quenching the steel into water/oil from austenitizing temperature range will produce martensite (brittle) structure at room temperature. In order to convert brittle martensite to less brittle and also to retain toughness, tempering process shall follow after quenching
During quenching, some % of austenite may retain to room temperature due to some of the alloying elements (austenitic stabilizing elements such as Mn, Ni, C) and cooling rate. This austenite may try to convert as secondary martensite when tempering treatment is carried out. Hence this martensite is called “untempered martensite” which is brittle in nature. This may contribute to the overall brittleness to the material/ structure.
Microstrural analysis can reveal the untempered martensite in the steel micro-structure.
Regards,
L. Prabhu kumar,
Sr. Principal Engineer,
Equipments & Materials Dept.,
Saipem India Projects Limited,
Nungambakkam High Road, Chennai - 600 034, India.
Tel:+91 44 43906588, Ext.: 588, Fax:+91 44 66840345,
Mobile Ph. No.: +91 9003010978.
From: material...@googlegroups.com [mailto:material...@googlegroups.com] On Behalf Of Kathalingam Babu
Sent: Tuesday, June 08, 2010 6:21
AM
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Mr. Babu,
The hardness of untempered martensite is determined almost entirely by its carbon content, as shown in the attached diagram.
Regards,
R. W. Warke
Robert
W. Warke, P.E.
Associate Professor of
Welding & Materials Joining
School of Engineering & Engineering Technology
LeTourneau University
From:
material...@googlegroups.com [mailto:material...@googlegroups.com] On
Behalf Of Kathalingam Babu
Sent: Tuesday, June 08, 2010 6:21 AM
To: material...@googlegroups.com
Subject: [MW:5437] Hardness of Untempered Martensite
Hi
----- Original Message -----From: Warke, Robert
--
You’re welcome, Mr. Babu. The previous figure does apply to alloy steels as well as to plain-carbon.
Alloy content in a ferritic steel strongly influences its hardenability, which is how easily martensite can be produced by quenching its austenite. Carbon content, on the other hand, determines the hardness of any martensite that is produced, and thus determines the maximum attainable hardness of a steel. The attached figure demonstrates both of these principles.
~RWW
These are AISI designations and the chemistry requirements are quite commonly published. Briefly the first two numbers indicate the alloy type and the last two numbers indicate the nominal carbon content. Thus for the figure shown you have carbon steel (1040) hardness vs. various alloy steels hardness all with the same nominal carbon content (~0.40%). The figure also shows that alloying content will affect the depth of hardening as demonstrated in the Jominy test. At the maximum cooling rate, at the quenched end of the Jominy specimen, the hardnesses are nearly the same for all the steels because martensite is formed almost exclusively. This is as expected, since the hardness of martensite is solely dependent on carbon content and all the steels have the same carbon content. As the cooling rate decreases (increasing distance from the quenched end of the specimen, i.e. DQE) the formation of martensite is dependent on the alloy content, thus you see a rapid fall off in the carbon steel hardness (1040) (no deliberate alloying elements) as opposed to alloy steels. The figure shows that various alloying schemes increase hardenablility more than others and is shown in the figure as higher hardness with distance from the quenched end.
You may find additional and more complete discussion of hardenability and the Jominy test in any basic metallurgy/materials textbook or a beginning book on heat treatment of steels.
John