Hello,
Unfortunately the inequality constraint does not yield a smooth manifold. Here is one way to think about it: for a vector x in R^n, the constraints ||x|| = 1 defines a sphere, which is a smooth surface; but the constraint ||x|| <= 1 defines a ball: that has a boundary (the sphere), which makes it not smooth. (Of course, it is still a "manifold with boundary", but Manopt does not have built-in tools for that.)
Best,
Nicolas