I've been experimenting printing molds in PLA for casting. The stuff I'm casting with is called Permastone, which is just plaster mixed with something to make it stronger. I got it at Hobby Lobby where I'm sure it's vastly overpriced and is probably the same stuff you can get online for about 15% of the cost.
I did a few simple tests to verify it works and then tried something more involved- an 8 sided box. The problem in designing the mold is to get something that you can not only pour the liquid in and get the shape you want, but also get the cast out of when it dries. I've only read about how to do it, but based on that my first tests didn't work out. I tried printing two-part molds in PLA but they weren't flexible enough to get the model out without breaking it.
So I went the other direction and broke the mold down into a lot of pieces that would be easy to take off one by one without putting any stress on the cast. In order to assemble the mold I used the CAD drawing of the box to design and print custom "clips" that fit the geometry accurately and held all the pieces to together.
This worked out better than I expected. Attached are four pics illustrating the process.
1. The first pic shows all the parts of the mold laid out.
2. The second pic is the assembled mold.
3. The third pic is the mold filled with plaster.
4. The last pic shows two completed casts. The one on the left is as it came out of the mold. The one on the right has been lightly sanded but nothing else.
The mold is reusable- both these casts were made from the same mold. Cleaning it between casts is just dipping the pieces in water and wiping with a paper towel.
I mean to make a top for the boxes the same way, which is an easy mold. But I'm not sure how to finish the boxes. I tried acrylic paint on an earlier model. It sealed well but the appearance was kind of ho-hum. The plaster has a certain softness to it I want to try to preserve in the finish.