I was going to suggest Smooth-on also. Their products can be found at Reynolds Advanced Material Locations.
You want to cast urethane into silicone to prevent the part bonding to the mold.

I was able to print the mold jackets for my parts also.
Take a look at that image. The Purple thing in the foreground is a 3 -part mold curing. the printed plastic around it is the mold jacket which I printed out. The purple things in the right upper middleground are parts for the same mold - a removable plug for casting a void inside the part.
The parts on the left in the orange molds are duplicates of the part that is between the two purple molds on the left. I glued it to a flat sheet of metal with a printed mold fence around it in order to cast the molds.
You can also see a second 3-part mold with removable mold jacket in the upper left.