2) You need to MEASURE the filament diameter, not just input various guesses. Your packing density / feedstockMultiplier calibration is wrong if you don't have the actual diameter inputted when you calibrate. Once you properly calibrate packing density once, you only have to measure diameter after that (except repeat for each extruder hardware and filament type combo.)
3) Drop your extrusion temp to 210C for PLA. Some people go lower. 230+ is way too high.
4) Re-purge your nozzle at the right temperature to make sure no crap is on there. Filament should extrude straight down during a load cycle. If it doesn't, you probably have a nozzle clog (possibly from printing too hot).
5) Be careful with spray canola. It may have other ingredients in it to reduce the viscosity for the spray mechanism. No way of knowing what that'll do. I would stick with regular non-spray oil. The optimal way to deliver canola seems to be a dampened sponge in a printed filament wiper (check Thingiverse).
I'm guessing you have crap in your nozzle and the high temp is simply reducing the viscosity enough to let you squeeze out some plastic for a while. But in the long run that's going to get worse, not better.