I have this exact setup. Re the location of the nano Io air, assuming the air signal is strong enough at the boiler in need to go next to the boiler and use the same power supply as the boiler.
If your don't then the boiler has power from two different circuits which is potentially dangerous.
Re the logic. Use an intelligent room controller for each zone and a new climate control to control the boiler itself. Have a look at the inputs, outputs and parameters and see how you get on.
Ask any further questions if you want
Andy
Andy
For Harry it needs to to be fed from the same fused spur that the boiler is fed from. If not someone will turn off the boiler fused spur and think the boiler is completely electrically isolated but it isn't and they could well get electrocuted.
If you are not confident about this then you really should have a partner help you. Because then there is the question of are the thermostat contacts 240v, a different voltage or volt free, and which terminal is the switched live. If you get that wrong you wreck your boiler