I've used the blue high density foam from 4D model shop before when doing jobs on my cnc mill.
Its pretty cool stuff with a fine structure so it picks up cuts and contours really well and you can run the toolpath at the highest rate. It makes a lot of dust though.
A cool thing I found with it is you can polish the surface up with vaseline after its been cut and it will smooth it up consideraly as well as sealing the pores. This I found a really useful way of making a plaster model/master from a digital shape in the shortest amount of time.*
*Well, as long as you dont have overhangs...
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