Can you reproduce with 3.81-1 in unstable?
For posterity, the useful information:
==837133== Syscall param socketcall.sendto(msg) points to uninitialised byte(s)
==837133== at 0x5A153D6: __libc_send (send.c:28)
==837133== by 0x5A153D6: send (send.c:23)
==837133== by 0xB083527: pt_Send (ptio.c:2002)
==837133== by 0xB01DFF7: ssl_DefSend (ssldef.c:105)
==837133== by 0xB0229C0: ssl_SendSavedWriteData (sslsecur.c:452)
==837133== by 0xB006839: ssl3_SendRecord (ssl3con.c:2568)
==837133== by 0xB006C2C: ssl3_FlushHandshakeMessages (ssl3con.c:2774)
==837133== by 0xB006C2C: ssl3_FlushHandshake (ssl3con.c:2747)
==837133== by 0xB00F5E4: ssl3_SendFinished (ssl3con.c:11944)
==837133== by 0xB00FB79: ssl3_SendClientSecondRound (ssl3con.c:8191)
==837133== by 0xB011A7A: ssl3_HandleServerHelloDone (ssl3con.c:8061)
==837133== by 0xB011A7A: ssl3_HandlePostHelloHandshakeMessage (ssl3con.c:12568)
==837133== by 0xB011A7A: ssl3_HandleHandshakeMessage (ssl3con.c:12479)
==837133== by 0xB014A74: ssl3_HandleHandshake (ssl3con.c:12653)
==837133== by 0xB014A74: ssl3_HandleNonApplicationData (ssl3con.c:13188)
==837133== by 0xB0153C0: ssl3_HandleRecord (ssl3con.c:13529)
==837133== by 0xB01B500: ssl3_GatherCompleteHandshake (ssl3gthr.c:561)
==837133== by 0xB01B500: ssl3_GatherCompleteHandshake (ssl3gthr.c:449)
==837133== by 0xB022A80: SSL_ForceHandshake (sslsecur.c:382)
==837133== by 0xADCC8D6: ssl_nss_handshake_cb (ssl-nss.c:371)
==837133== by 0x1824B1: pidgin_io_invoke (gtkeventloop.c:73)
==837133== by 0x54BBA9E: g_main_dispatch (gmain.c:3417)
==837133== by 0x54BBA9E: g_main_context_dispatch (gmain.c:4135)
==837133== by 0x54BBE57: g_main_context_iterate.constprop.0 (gmain.c:4211)
==837133== by 0x54BC10E: g_main_loop_run (gmain.c:4411)
==837133== by 0x4C57B29: gtk_main (in /usr/lib/x86_64-linux-gnu/libgtk-x11-2.0.so.0.2400.33)
==837133== by 0x145D7B: main (gtkmain.c:948)
==837133== Address 0x1b82e246 is 534 bytes inside a block of size 1,553 alloc'd
==837133== at 0x484582F: realloc (vg_replace_malloc.c:1437)
==837133== by 0xB2114A1: PORT_Realloc_Util (secport.c:101)
==837133== by 0xB01E1E4: sslBuffer_Grow (sslencode.c:50)
==837133== by 0xB01E1E4: sslBuffer_Grow (sslencode.c:31)
==837133== by 0xB01E42B: sslBuffer_Append (sslencode.c:82)
==837133== by 0xB006817: ssl3_SendRecord (ssl3con.c:2559)
==837133== by 0xB006C2C: ssl3_FlushHandshakeMessages (ssl3con.c:2774)
==837133== by 0xB006C2C: ssl3_FlushHandshake (ssl3con.c:2747)
==837133== by 0xB00F5E4: ssl3_SendFinished (ssl3con.c:11944)
==837133== by 0xB00FB79: ssl3_SendClientSecondRound (ssl3con.c:8191)
==837133== by 0xB011A7A: ssl3_HandleServerHelloDone (ssl3con.c:8061)
==837133== by 0xB011A7A: ssl3_HandlePostHelloHandshakeMessage (ssl3con.c:12568)
==837133== by 0xB011A7A: ssl3_HandleHandshakeMessage (ssl3con.c:12479)
==837133== by 0xB014A74: ssl3_HandleHandshake (ssl3con.c:12653)
==837133== by 0xB014A74: ssl3_HandleNonApplicationData (ssl3con.c:13188)
==837133== by 0xB0153C0: ssl3_HandleRecord (ssl3con.c:13529)
==837133== by 0xB01B500: ssl3_GatherCompleteHandshake (ssl3gthr.c:561)
==837133== by 0xB01B500: ssl3_GatherCompleteHandshake (ssl3gthr.c:449)
==837133== by 0xB022A80: SSL_ForceHandshake (sslsecur.c:382)
==837133== by 0xADCC8D6: ssl_nss_handshake_cb (ssl-nss.c:371)
==837133== by 0x1824B1: pidgin_io_invoke (gtkeventloop.c:73)
==837133== by 0x54BBA9E: g_main_dispatch (gmain.c:3417)
==837133== by 0x54BBA9E: g_main_context_dispatch (gmain.c:4135)
==837133== by 0x54BBE57: g_main_context_iterate.constprop.0 (gmain.c:4211)
==837133== by 0x54BC10E: g_main_loop_run (gmain.c:4411)
==837133== by 0x4C57B29: gtk_main (in /usr/lib/x86_64-linux-gnu/libgtk-x11-2.0.so.0.2400.33)
==837133== by 0x145D7B: main (gtkmain.c:948)
==837133== Uninitialised value was created by a stack allocation
==837133== at 0xB005DC0: ssl3_MACEncryptRecord (ssl3con.c:2104)