Hi John,
OpenStreetMap used to give you the bounding box coordinates when you exported an image from their site. Unfortunately, it's not as straightforward with the newly redesigned site, however it is still possible. Go to
http://www.openstreetmap.org, zoom in to your area of interest, and click the "Export Data" link in the lower left-hand corner of the page. You don't want to export the raw data, so to get an image you have to click on the share tool on the black toolbar (second one up from the bottom). Now make note of the bounding coordinates on the export screen (North, East, South, West). Use these coordinates when you load your map image into Leaflet like so:
var imageUrl = 'map.png',
imageBounds = [[South, West], [North, East]];
L.imageOverlay(imageUrl, imageBounds).addTo(map);
Where South, West, North, and East are the coordinates from the export screen.