Hi Benjamin,
I think is due to the fact that you can choose to assign different values to the internal or the external surface of a material. The most common case is aluminium that has an internal face not painted and the external one painted.
Anyway, if you check my last post, I noticed that each time you change that property, when you open a second time the boundary condition after assigning a value (or the cavity to which you change it), you'll find the original value and this can bring to lose control of your operations.
Alessandro