There are not many simulation software that will do the ray trace radiosity heat transfer simulation.
In most cases with curtain wall or systems with very few air gaps will not make much difference as most of the heat flow is through conduction.
For fenestration with many air gaps at thermal breaks there would be a notable difference.
Air gaps with an all metal surrounding will have small delta-T between walls due to high conduction. With cavities that have a dominant radation flow direction will also probably have little difference because the heat flow in one direction will likely govern.
Here is an example:
https://www.flixo.com/thermal-bridge/en-iso-10077-2/
Technically the NFRC standards reference ISO15099 which has not adopted the radiosity method so doesn’t really affect US.
Europe mainly uses ISO10077.
Yalin