AVE is not a reliability measure, but used as a sort of validity check. If you have a good/reliable measure, then most of the indicators' variance should be attributable to the construct they were designed to measure. So that is what AVE quantifies: how much variance (on average across indicators) is "extracted" from / attributable to the common factor. The common-factor variance component for each indicator is the factor variance times the squared factor loading:
Lambda %*% Psi %*% Lambda.
In a standardized solution, Psi = 1, so the squared loading is the common-factor variance component. Furthermore, the standardized error variance is the proportion not attributable to the common factor. So I suppose in models with simple structure, one could just average the standardized error variances, then take 1 minus that to calculate AVE. But I don't have the paper in front of me to verify that.
Terrence D. Jorgensen (he, him, his)Assistant Professor, Methods and StatisticsResearch Institute for Child Development and Education, the University of Amsterdamhttp://www.uva.nl/profile/t.d.jorgensen