Two thoughts...
First, I am not a statistician but it has been my understanding that the chi-square difference test is more accurate and the preferred test for core hypotheses. Moreover, following the lead of Cohen, Cohen, West & Aiken's regression book, I might proceed as follows.
1. Fit a model with no equality constraints across groups.
2. Using parameter labels, give all the effect coefficients of interest the same label in each group and fit this model which constrains them all to equality.
3. Use the chi-square difference test as an omnibus test of the hypothesis that they are all equal across groups.
a. If the difference does not reach statistical significance then stop and conclude that they are all equal across groups.
b. If the difference does reach statistical significance, then proceed to step 4.
4. Compare the first model with no equality constraints to a model constraining only one effect coefficient to equality between groups and repeat for each coefficient of interest. Use the results to draw conclusions about which are equal across groups.
Note: The idea is that the omnibus test "protects" the single-coefficient tests from alpha inflation. The reason for using the model with no constraints to test individual parameters is that the chi-square difference test assumes that the nesting model is correctly specified and the model with the fewest constraints has the best chance of meeting this assumption.
Second, it seems to strong to say that the test is not valid without measurement invariance. As a statistical test of the equality of two parameters, it seems to me that the test remains valid without measurement invariance. Nonetheless, any differences have two potential explanations (a) differences in causal effects or (b) differences in measurement. So, if one wishes to assert the former explanation, then the latter functions as a plausible rival hypothesis and one can view this as a case of Campbellian validity. However, that is the validity of the inference regarding hypothesis a, not the validity of the test of the equality constraint.
Please correct me if I am missing something.
Keith