you will have to download the latest version of LAStools (as I found a small bug in the library when I developed the workflow below that can extract those "ancient" or "raw" 8 bit classification codes that were allowed in the initial 1.0 version of LAS but changed later to 5 bit classification codes.
===================================================================
E:\LAStools\bin>lasinfo -i sample.laz
lasinfo (180620) report for 'sample.laz'
reporting all LAS header entries:
file signature: 'LASF'
file source ID: 0
global_encoding: 1
project ID GUID data 1-4: 00000000-0000-0000-0000-000000000000
version major.minor: 1.2
system identifier: ''
generating software: 'LASzip DLL 2.4 r0 (150731)'
file creation day/year: 151/2018
header size: 227
offset to point data: 227
number var. length records: 0
point data format: 1
point data record length: 28
number of point records: 1705564
number of points by return: 1300757 275927 95278 27228 5475
scale factor x y z: 0.01 0.01 0.01
offset x y z: 0 0 0
min x y z: 6335725.72 1936317.47 1376.31
max x y z: 6336252.96 1936998.07 1760.36
LASzip compression (version 2.4r0 c2 50000): POINT10 2 GPSTIME11 2
reporting minimum and maximum for all LAS point record entries ...
X 633572572 633625296
Y 193631747 193699807
Z 137631 176036
intensity 1 23546
return_number 0 7
number_of_returns 0 7
edge_of_flight_line 0 0
scan_direction_flag 0 0
classification 1 25
scan_angle_rank -29 29
user_data 0 0
point_source_ID 5625 5625
gps_time 199138704.649335 199138714.407946
number of first returns: 1300757
number of intermediate returns: 128855
number of last returns: 1300787
number of single returns: 1024865
WARNING: for return 1 real number of points by return (1300752) is different from header entry (1300757).
WARNING: there are 5 points with return number 0
WARNING: there are 805 points with return number 6
WARNING: there are 94 points with return number 7
overview over number of returns of given pulse: 1024825 361298 204150 87012 23350 4266 623
WARNING: there are 40 points with a number of returns of given pulse of 0
histogram of classification of points:
1701789 unclassified (1)
1381 rail (10)
463 Reserved for ASPRS Definition (21)
1931 Reserved for ASPRS Definition (25)
+-> flagged as withheld: 2394
===================================================================
E:\LAStools\bin>las2las -i sample.laz -set_point_type 6 -o sample_pt6.laz
===================================================================
E:\LAStools\bin>lasinfo -i sample_pt6.laz
lasinfo (180620) report for 'sample_pt6.laz'
reporting all LAS header entries:
file signature: 'LASF'
file source ID: 0
global_encoding: 1
project ID GUID data 1-4: 00000000-0000-0000-0000-000000000000
version major.minor: 1.4
system identifier: 'LAStools (c) by rapidlasso GmbH'
generating software: 'las2las (version 180620)'
file creation day/year: 151/2018
header size: 375
offset to point data: 375
number var. length records: 0
point data format: 6
point data record length: 30
number of point records: 0
number of points by return: 0 0 0 0 0
scale factor x y z: 0.01 0.01 0.01
offset x y z: 0 0 0
min x y z: 6335725.72 1936317.47 1376.31
max x y z: 6336252.96 1936998.07 1760.36
start of waveform data packet record: 0
start of first extended variable length record: 0
number of extended_variable length records: 0
extended number of point records: 1705564
extended number of points by return: 1300752 275927 95278 27228 5475 805 94 0 0 0 0 0 0 0 0
LASzip compression (version 3.2r4 c3 50000): POINT14 3
reporting minimum and maximum for all LAS point record entries ...
X 633572572 633625296
Y 193631747 193699807
Z 137631 176036
intensity 1 23546
return_number 0 7
number_of_returns 0 7
edge_of_flight_line 0 0
scan_direction_flag 0 0
classification 1 25
scan_angle_rank -29 29
user_data 0 0
point_source_ID 5625 5625
gps_time 199138704.649335 199138714.407946
extended_return_number 0 7
extended_number_of_returns 0 7
extended_classification 1 25
extended_scan_angle -4833 4833
extended_scanner_channel 0 0
number of first returns: 1300757
number of intermediate returns: 128855
number of last returns: 1300787
number of single returns: 1024865
WARNING: there are 5 points with return number 0
overview over extended number of returns of given pulse: 1024825 361298 204150 87012 23350 4266 623 0 0 0 0 0 0 0 0
WARNING: there are 40 points with a number of returns of given pulse of 0
histogram of classification of points:
1701789 unclassified (1)
1381 rail (10)
463 Reserved for ASPRS Definition (21)
1931 Reserved for ASPRS Definition (25)
+-> flagged as withheld: 2394
===================================================================
E:\LAStools\bin>las2las -i sample_pt6.laz -move_ancient_to_extended_classification -o sample_pt6_moved.laz
===================================================================
E:\LAStools\bin>lasinfo -i sample_pt6_moved.laz
lasinfo (180620) report for 'sample_pt6_moved.laz'
reporting all LAS header entries:
file signature: 'LASF'
file source ID: 0
global_encoding: 1
project ID GUID data 1-4: 00000000-0000-0000-0000-000000000000
version major.minor: 1.4
system identifier: 'LAStools (c) by rapidlasso GmbH'
generating software: 'las2las (version 180620)'
file creation day/year: 151/2018
header size: 375
offset to point data: 375
number var. length records: 0
point data format: 6
point data record length: 30
number of point records: 0
number of points by return: 0 0 0 0 0
scale factor x y z: 0.01 0.01 0.01
offset x y z: 0 0 0
min x y z: 6335725.72 1936317.47 1376.31
max x y z: 6336252.96 1936998.07 1760.36
start of waveform data packet record: 0
start of first extended variable length record: 0
number of extended_variable length records: 0
extended number of point records: 1705564
extended number of points by return: 1300752 275927 95278 27228 5475 805 94 0 0 0 0 0 0 0 0
LASzip compression (version 3.2r4 c3 50000): POINT14 3
reporting minimum and maximum for all LAS point record entries ...
X 633572572 633625296
Y 193631747 193699807
Z 137631 176036
intensity 1 23546
return_number 0 7
number_of_returns 0 7
edge_of_flight_line 0 0
scan_direction_flag 0 0
classification 1 10
scan_angle_rank -29 29
user_data 0 0
point_source_ID 5625 5625
gps_time 199138704.649335 199138714.407946
extended_return_number 0 7
extended_number_of_returns 0 7
extended_classification 1 153
extended_scan_angle -4833 4833
extended_scanner_channel 0 0
number of first returns: 1300757
number of intermediate returns: 128855
number of last returns: 1300787
number of single returns: 1024865
WARNING: there are 5 points with return number 0
overview over extended number of returns of given pulse: 1024825 361298 204150 87012 23350 4266 623 0 0 0 0 0 0 0 0
WARNING: there are 40 points with a number of returns of given pulse of 0
histogram of classification of points:
1701789 unclassified (1)
1381 rail (10)
histogram of extended classification of points:
463 extended classification (149)
1931 extended classification (153)
E:\LAStools\bin>las2txt -i sample_pt6_moved.laz -keep_extended_class 149 153 -parse txyznrc -stdout | more
199138705.596634 6335834.67 1936763.95 1415.65 3 2 149
199138705.604133 6335834.94 1936763.82 1416.17 2 1 149
199138705.611632 6335835.49 1936763.58 1416.76 3 2 149
199138705.619133 6335835.79 1936763.42 1417.35 2 1 149
199138705.641627 6335836.80 1936763.54 1418.37 2 1 149
199138705.664126 6335837.79 1936763.14 1419.85 2 1 149
199138705.671625 6335838.31 1936763.07 1420.27 2 1 149
199138705.694123 6335839.36 1936762.57 1421.98 3 1 149
199138705.709121 6335839.98 1936762.37 1422.86 3 1 149
199138705.724117 6335840.70 1936762.46 1423.62 3 1 149
199138705.731617 6335841.13 1936762.20 1424.21 3 1 149
199138705.986598 6335854.20 1936758.53 1437.73 2 1 153
199138705.994097 6335854.62 1936758.39 1437.53 2 1 153
199138706.039102 6335858.00 1936757.45 1437.10 2 1 153
199138706.069106 6335860.12 1936756.84 1436.78 2 1 153
199138706.091607 6335861.80 1936756.34 1436.41 2 1 153
199138706.099108 6335862.29 1936756.17 1436.35 2 1 153
199138706.106610 6335862.68 1936756.14 1436.35 2 1 153
199138706.114105 6335863.11 1936756.33 1436.68 2 1 153
199138706.114110 6335863.20 1936755.97 1436.18 2 1 153
199138706.121609 6335863.86 1936755.80 1436.22 2 1 153
199138706.151613 6335865.95 1936755.16 1435.86 2 1 153
199138706.159113 6335866.64 1936755.02 1435.86 2 1 153
199138706.166614 6335867.17 1936754.86 1435.76 2 1 153
199138706.181614 6335868.02 1936754.78 1435.69 2 1 153
199138706.189115 6335868.58 1936754.71 1435.73 2 1 153
199138706.219119 6335870.74 1936753.94 1435.40 2 1 153
199138706.249120 6335872.93 1936753.34 1435.14 2 1 153
199138706.256622 6335873.33 1936753.14 1435.04 2 1 153