Thanks, got it working with jnius:
def hook_keyboard(self, window, key, *largs):
if key == 27:
PythonActivity = jnius.autoclass('org.renpy.android.PythonActivity')
Intent = jnius.autoclass('android.content.Intent')
intent = Intent(Intent.ACTION_MAIN)
intent.addCategory(Intent.CATEGORY_HOME)
intent.setFlags(Intent.FLAG_ACTIVITY_NEW_TASK)
currentActivity = jnius.cast('android.app.Activity', PythonActivity.mActivity)
currentActivity.startActivity(intent)
return True