nikvay amadea kaelee
Chris Richard
The mathematical formulations of quantum mechanics are those mathematical formalisms that permit a rigorous description of quantum mechanics. This mathematical formalism uses mainly a part of functional analysis, especially Hilbert spaces, which are a kind of linear space. Such are distinguished from mathematical formalisms for physics theories developed prior to the early 1900s by the use of abstract mathematical structures, such as infinite-dimensional Hilbert spaces (L2 space mainly), and operators on these spaces. In brief, values of physical observables such as energy and momentum were no longer considered as values of functions on phase space, but as eigenvalues; more precisely as spectral values of linear operators in Hilbert space.[1]
These formulations of quantum mechanics continue to be used today. At the heart of the description are ideas of quantum state and quantum observables, which are radically different from those used in previous models of physical reality. While the mathematics permits calculation of many quantities that can be measured experimentally, there is a definite theoretical limit to values that can be simultaneously measured. This limitation was first elucidated by Heisenberg through a thought experiment, and is represented mathematically in the new formalism by the non-commutativity of operators representing quantum observables.
In the 1890s, Planck was able to derive the blackbody spectrum, which was later used to avoid the classical ultraviolet catastrophe by making the unorthodox assumption that, in the interaction of electromagnetic radiation with matter, energy could only be exchanged in discrete units which he called quanta. Planck postulated a direct proportionality between the frequency of radiation and the quantum of energy at that frequency. The proportionality constant, h, is now called Planck's constant in his honor.
Werner Heisenberg's matrix mechanics was the first successful attempt at replicating the observed quantization of atomic spectra. Later in the same year, Schrdinger created his wave mechanics. Schrdinger's formalism was considered easier to understand, visualize and calculate as it led to differential equations, which physicists were already familiar with solving. Within a year, it was shown that the two theories were equivalent.
The application of the new quantum theory to electromagnetism resulted in quantum field theory, which was developed starting around 1930. Quantum field theory has driven the development of more sophisticated formulations of quantum mechanics, of which the ones presented here are simple special cases.
A related topic is the relationship to classical mechanics. Any new physical theory is supposed to reduce to successful old theories in some approximation. For quantum mechanics, this translates into the need to study the so-called classical limit of quantum mechanics. Also, as Bohr emphasized, human cognitive abilities and language are inextricably linked to the classical realm, and so classical descriptions are intuitively more accessible than quantum ones. In particular, quantization, namely the construction of a quantum theory whose classical limit is a given and known classical theory, becomes an important area of quantum physics in itself.
Finally, some of the originators of quantum theory (notably Einstein and Schrdinger) were unhappy with what they thought were the philosophical implications of quantum mechanics. In particular, Einstein took the position that quantum mechanics must be incomplete, which motivated research into so-called hidden-variable theories. The issue of hidden variables has become in part an experimental issue with the help of quantum optics.
A physical system is generally described by three basic ingredients: states; observables; and dynamics (or law of time evolution) or, more generally, a group of physical symmetries. A classical description can be given in a fairly direct way by a phase space model of mechanics: states are points in a phase space formulated by symplectic manifold, observables are real-valued functions on it, time evolution is given by a one-parameter group of symplectic transformations of the phase space, and physical symmetries are realized by symplectic transformations. A quantum description normally consists of a Hilbert space of states, observables are self-adjoint operators on the space of states, time evolution is given by a one-parameter group of unitary transformations on the Hilbert space of states, and physical symmetries are realized by unitary transformations. (It is possible, to map this Hilbert-space picture to a phase space formulation, invertibly. See below.)
Separability is a mathematically convenient hypothesis, with the physical interpretation that the state is uniquely determined by countably many observations. Quantum states can be identified with equivalence classes in H, where two vectors (of length 1) represent the same state if they differ only by a phase factor.[4] As such, quantum states form a ray in projective Hilbert space, not a vector. Many textbooks fail to make this distinction, which could be partly a result of the fact that the Schrdinger equation itself involves Hilbert-space "vectors", with the result that the imprecise use of "state vector" rather than ray is very difficult to avoid.[5]
The Hilbert space of a composite system is the Hilbert space tensor product of the state spaces associated with the component systems. For a non-relativistic system consisting of a finite number of distinguishable particles, the component systems are the individual particles.
In the presence of quantum entanglement, the quantum state of the composite system cannot be factored as a tensor product of states of its local constituents; Instead, it is expressed as a sum, or superposition, of tensor products of states of component subsystems. A subsystem in an entangled composite system generally cannot be described by a state vector (or a ray), but instead is described by a density operator; Such quantum state is known as a mixed state. The density operator of a mixed state is a trace class, nonnegative (positive semi-definite) self-adjoint operator ρ normalized to be of trace 1. In turn, any density operator of a mixed state can be represented as a subsystem of a larger composite system in a pure state (see purification theorem).
Physical observables are represented by Hermitian matrices on H. Since these operators are Hermitian, their eigenvalues are always real, and represent the possible outcomes/results from measuring the corresponding observable. If the spectrum of the observable is discrete, then the possible results are quantized.
When a measurement is performed, only one result is obtained (according to some interpretations of quantum mechanics). This is modeled mathematically as the processing of additional information from the measurement, confining the probabilities of an immediate second measurement of the same observable. In the case of a discrete, non-degenerate spectrum, two sequential measurements of the same observable will always give the same value assuming the second immediately follows the first. Therefore, the state vector must change as a result of measurement, and collapse onto the eigensubspace associated with the eigenvalue measured.
Postulates II.c is sometimes called the "state update rule" or "collapse rule"; Together with the Born rule (Postulates II.a and II.b), they form a complete representation of measurements, and are sometimes collectively called the measurement postulate(s).
Note that the projection-valued measures (PVM) described in the measurement postulate(s) can be generalized to positive operator-valued measures (POVM), which is the most general kind of measurement in quantum mechanics. A POVM can be understood as the effect on a component subsystem when a PVM is performed on a larger, composite system (see Naimark's dilation theorem).
Though it is possible to derive the Schrdinger equation, which describes how a state vector evolves in time, most texts assert the equation as a postulate. Common derivations include using the de Broglie hypothesis or path integrals.
In quantum mechanics, two particles can be distinguished from one another using two methods. By performing a measurement of intrinsic properties of each particle, particles of different types can be distinguished. Otherwise, if the particles are identical, their trajectories can be tracked which distinguishes the particles based on the locality of each particle. While the second method is permitted in classical mechanics, (i.e. all classical particles are treated with distinguishability), the same cannot be said for quantum mechanical particles since the process is infeasible due to the fundamental uncertainty principles that govern small scales. Hence the requirement of indistinguishability of quantum particles is presented by the symmetrization postulate. The postulate is applicable to a system of bosons or fermions, for example, in predicting the spectra of helium atom. The postulate, explained in the following sections, can be stated as follows:
Exceptions can occur when the particles are constrained to two spatial dimensions where existence of particles known as anyons are possible which are said to have a continuum of statistical properties spanning the range between fermions and bosons.[9] The connection between behaviour of identical particles and their spin is given by spin statistics theorem.
It can be shown that two particles localized in different regions of space can still be represented using a symmetrized/antisymmetrized wavefunction and that independent treatment of these wavefunctions gives the same result.[10] Hence the symmetrization postulate is applicable in the general case of a system of identical particles.
If a physical system of identical particles is given, wavefunction of all particles can be well known from observation but these cannot be labelled to each particle. Thus, the above exchanged wavefunction represents the same physical state as the original state which implies that the wavefunction is not unique. This is known as exchange degeneracy.[11]
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