It looks like Mahmoud beat me to it, but yes - off the top of my head, the national archival portal in Canada, ArchivesCanada, includes approximately 905,000 records from 780 different institutions. See:
It has admittedly not been regularly updated, so I can't speak to how ongoing maintenance would go if you were trying to have all institutions use it as their primary catalogue - I wouldn't recommend that for 780 different institutions! The original intention here was NOT that all Canadian archives login and USE a single AtoM instance. Rather, each province and territory has its own regional portal (many of which are also AtoM instances), and these regional portals would regularly coordinate with their users to deliver new updates and content.
Some of the regional portals are quite large as well, and in many cases are actively used by multiple different institutions. See for example:
There are a couple other multi-repository community portal sites I am aware of in Canada, though these are a bit smaller overall:
Many of these sites do use AtoM as full multi-repository sites, but returning the ArchivesCanada use case, it is important to clarify before you go further with this project:
AtoM's current multi-repository functionality was not designed with full multi-tenancy in mind (i.e. where each institution has access to private versions of all the entities in AtoM). Instead, AtoM currently supports multi-repository access functionality. However, if you need full isolation between your users, there are some serious limitations with the current implementation. I have talked about these limitations previously in the forum - see for example:
Hopefully other international users will reply and share their examples and experiences - or you may find more by perusing the example user list on our wiki:
Cheers,
Dan Gillean, MAS, MLIS