Okay, I haven't got finished PHP scripts yet but (for me, anyway) it's the way to go.
Extract the contents to C:\php (or any other folder, doesn't have to be on C: and doesn't have to be the same drive as your photos)
Add C:\php (or your chosen path) to your "Path" Environment variable (Right click My Computer, go to Advanced System Settings, click Environment Variables button. Or search "Environment Variables" in Settings)
Open a command line prompt and type php --version [ENTER] to confirm it's working.
If you haven't got one already, I'd recommend setting up a project folder, with a "Photos" folder in it containing the full set of photos. PHP scripts will go in the project folder.